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SYNTHESIS, CHARACTERISATION AND REACTIONS OF CATIONIC COMPLEXES OF ARYLANTIMONY(III) CHLORIDES ArnSbCl3-n WITH PERCHLORATE AND TETRAFLUOROBORATE ANIONS
Ram Nath Prasad Yadav
Department of Chemistry, Tribhuvan University, Thakur Ram Multiple Campus, Birganj, Nepal
Several hitherto unreported cationic complexes of the general formula [Ar2SbL][Y] and [ArSbL2][Y]2 [ Where, Ar = C6H5, L = a-Picoline, Pyridine, Ph3AsO, hexamethyl phosphoramide (HMPA), thiourea (TU) and Y = ClO4- BF4- ] have been synthesized and characterized by solid state IR, 1H NMR, elemental analysis, conductance and molecular weight measurements. The physico-chemical data, cations [Ar2SbL]+1 and[ArSbL2]+2 are assigned a pyramidal structure.
Key Words: Arylantimony(III) chloride, Cationic complex, IR spectra, Elemental analysis, Molecular weight measurement, Perchlorate, Tetrafluoroborate.